Lithium Disilicate
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Lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid el ...
di
silicate In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...
(Li2Si2O5) is a
chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
that is a glass ceramic. It is widely used as a dental ceramic due to its strength, machinability and translucency.


Use

Lithium disilicate has found applications in
dentistry Dentistry, also known as dental medicine and oral medicine, is the branch of medicine focused on the teeth, gums, and mouth. It consists of the study, diagnosis, prevention, management, and treatment of diseases, disorders, and conditions o ...
as a dental ceramic material for dental restorations such as
crowns A crown is a traditional form of head adornment, or hat, worn by monarchs as a symbol of their power and dignity. A crown is often, by extension, a symbol of the monarch's government or items endorsed by it. The word itself is used, partic ...
,
bridges A bridge is a structure built to Span (engineering), span a physical obstacle (such as a body of water, valley, road, or rail) without blocking the way underneath. It is constructed for the purpose of providing passage over the obstacle, whic ...
, and veneers in the form of Li2Si2O5. Lithium disilicate has an unusual microstructure that consists of many randomly oriented small and interlocking plate-like needle-like crystals. This structure causes cracks to be deflected, blunted, and/or to branch, which prevents cracks from growing. Lithium disilicate has a biaxial flexible strength in the range of 360 MPa to 400 MPa; in comparison, for metal ceramics this is around 80 to 100 MPa, for veneered
zirconia Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabi ...
it is approximately 100 MPa, and for leucite
glass ceramic Glass-ceramics are polycrystalline materials produced through controlled crystallization of base glass, producing a fine uniform dispersion of crystals throughout the bulk material. Crystallization is accomplished by subjecting suitable glasses to ...
it is approximately 150 to 160 MPa. It has high hardness (5.92 +/- 0.18 GPa) and fracture toughness (3.3 +/- 0.14 MPa m1/2). In addition, it can be made to have an appearance that very closely resembles that of natural human teeth. Lithium disilicate is also used as a non-conductive seal, enamel or feed-through insulator in nickel superalloys or stainless steel, as it has a high thermal expansion.


References

{{Lithium compounds Inorganic silicon compounds Lithium compounds